WHY NEED THERMAL PASTE?

The surface of a CPU or a heatsink is never entirely flat. If you place a heatsink directly on a CPU, there will be tiny (invisible) gaps between the two. Since air conducts heat poorly, these gaps have a very negative effect on the heat transfer. Therefore, an interface material with a high thermal conductivity is needed to fill these gaps, and thus improve heat conductivity between CPU and heatsink. Most standard thermal compound consists of silicone. However, silicone doesn't have a high thermal conductivity, so they also contains zinc oxide to improve this. The zinc oxide also explains its white colour. High-End thermal compounds are usually silicone-free, and use metal-based additives (e.g. aluminum oxide or nitride, or even pulverized silver!) instead of Zinc Oxide.

credit to forum.lowyat.net

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